Since the original question isn't restricted to sci-fi subjects, here's my standard list for FineScale's occasional kit polls:
1/700 ships:
USS Langley (CV-1), USS Ranger (CV-4) and USS Wasp (CV-7)
1/48 aircraft:
Fieseler Fi-167, the Germans' purpose-designed torpedo plane
C-46 Commando (I always wished Monogram would have brought this out, when they issued the C-47 when I was a kid)
Curtiss F9C Sparrowhawk
1/32 aircraft:
Curtiss F11C Goshawk
Curtiss SBC
1/20 sci-fi:
I'd like to see Kow-san bring out a 1/20 Nutrocker and Dollhouse, and 1/20 versions of the armored walker kits, like the Greif.
Other sci-fi:
I'd like to see an injection-molded kit of Serenity. Not likely to happen, though.